Crystal structure of chlorido-(5-acetyl-2-(5-methylpyridin-2-yl)benzen-1-ido-κ2C,N)-pyridine-κN-palladium(II), C19H17ClN2OPd
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چکیده
منابع مشابه
Chlorido(4-methylpyridin-2-amine-κN 1)(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
In the title complex, [Cu(C13H11N2O)Cl(C6H8N2)], the Cu(II) atom adopts a distorted tetra-hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl-idene 2-amino-pyridine, and by the 2-amino-pyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-yl-imino ligand are not invo...
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The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-...
متن کاملCrystal structure of (Z)-4-methylbenzyl 3-[1-(5-methylpyridin-2-yl)ethylidene]dithiocarbazate1
In the title dithiocarbazate compound, C17H19N3S2, the central CN2S2 residue is essentially planar (r.m.s. deviation = 0.0288 Å) and forms dihedral angles of 9.77 (8) and 77.47 (7) with the substituted-pyridyl and p-tolyl rings, respectively, indicating a highly twisted molecule; the dihedral angle between the rings is 85.56 (8) . The configuration about the C N bond is Z, which allows for the ...
متن کاملBis[5-chloro-2-(phenyldiazenyl-κN 2)pyridine-κN]bis(thiocyanato-κN)iron(II)
In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio-cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl-diazen-yl)pyridine ligands, generating a fairly regular FeN(6) octa-hedral coordination geometry. The thio-cyanate ions are in a cis disposition and the pyridine N atoms are in a trans orientation. In the cryst...
متن کاملBis[3-(pyrazin-2-yl)-5-(pyridin-2-yl-κN)-1,2,4-triazol-1-ido-κN 1]copper(II)
In the mononuclear title complex, [Cu(C(11)H(7)N(6))(2)], the Cu(II) atom lies on a crystallographic inversion centre and is coordinated by four N atoms from two bidentate chelate monoanionic 3-(pyrazin-2-yl)-5-(pyridin-2-yl-1,2,4-triazol-1-ido ligands, two from the triazolide rings [Cu-N = 1.969 (2) Å] and two from the pyridine rings [Cu-N = 2.027 (2) Å], giving a slightly distorted square-pla...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2019
ISSN: 2197-4578,1433-7266
DOI: 10.1515/ncrs-2019-0365